N-(4-Methylphenyl)-3-nitropyridin-2-amine

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N-(4-Chloro­phen­yl)-3-nitro­pyridin-2-amine

In the title compound, C(11)H(8)ClN(3)O(2), the presence of intra-molecular N-H⋯O and C-H⋯N inter-actions help to establish an almost planar mol-ecule [dihedral angle between the pyridine and benzene rings = 9.89 (8)° and r.m.s. deviation for all 17 non-H atoms = 0.120 Å]. Supra-molecular tapes feature in the crystal packing whereby dimeric aggregates sustained by pairs of C-H⋯O inter-actions a...

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4-Methyl-N-(3-methyl­phen­yl)pyridin-2-amine

The title amine, C(13)H(14)N(2), is twisted with a dihedral angle between the rings of 60.07 (9)°. The amine N-H group and pyridine N atom are syn allowing for the formation of centrosymmetric eight-membered {⋯HNCN}(2) synthons via N-H⋯N hydrogen bonds. The two-mol-ecule aggregates are sustained in the three-dimensional crystal packing via C-H⋯π and π-π inter-actions [centroid-centroid distance...

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N-(4-Chloro­phen­yl)-4-methyl­pyridin-2-amine

In the title compound, C(12)H(11)ClN(2), the dihedral angle between the benzene and pyridyl rings is 48.03 (8)°. Twists are also evident in the mol-ecule, in particular about the N(a)-C(b) (a = amine and b = benzene) bond [C-N-C-C = -144.79 (18)°]. In the crystal, inversion dimers linked by pairs of N-H⋯N hydrogen bonds result in the formation of eight-membered {⋯NCNH}(2) synthons [or R(2) (2)(...

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N,N′-(4-Chloro­benzyl­idene)dipyrimidin-2-amine

The title compound, C(15)H(13)ClN(6), contains two pyrimidine rings and one benzene ring, where the dihedral angle between the planes through the pyrimidine rings is 81.57 (10)°, and those between the pyrimidine rings and the benzene ring are 84.02 (8) and 89.46 (7)°, indicating that the three rings are almost perpendicular. In the crystal, inter-molecular N-H⋯N hydrogen bonds link the mol-ecul...

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N-(3-Chloro­phen­yl)-3-nitro­pyridin-2-amine

The dihedral angle between the benzene and pyridyl rings in the title compound, C(11)H(8)ClN(3)O(2), is 22.65 (10)°, indicating a twisted mol-ecule. The amine H and nitro O atoms form a donor-acceptor pair for an intra-molecular N-H⋯O hydrogen bond so that the nitro group is almost coplanar with the pyridine ring to which it is connected [O-N-C-C torsion angle = 7.4 (3)°]. The pyridine N and Cl...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2010

ISSN: 1600-5368

DOI: 10.1107/s1600536810033040